This is due to the most important fact regarding borate; borate helps stabilize the pH of your water (See relationship between Chlorine and pH).
From what we are reading, the main reason for the 50 ppm maximum recommendation is health and safety, to prevent long-term exposure problems such as reproductive risks in young males. Opinions on the matter range from "borates remove CO2 from the water and starve algae" and "borates are herbicides" to "borates suppress pH to keep it lower so chlorine is more effective at killing algae.". This means algae is a lot less likely to form in the water. Master pool chemistry with the Orenda pool chemical dosing calculator. Pool algae is an unfortunate yet common problem many pool owners face. This is where 50% of the acid is present along with 50% of its conjugate base. This one is subjective. The first is preventing algae and calcium scaling on the top of the pool surface. WaterShapes January 6th, 2022 Simplicity in Panama, Mediation, Looking forward in 22, and more. If the pool has a Saltwater Chlorine Generator (SWG), borate is especially helpful because in the process of making chlorine from salt, SWGs produce a high pH. They are most effective between 30-50 ppm, much like cyanuric acid.
Saltwater vs. Chlorine Sanitation Pros and Cons for Swimming Pools, Swimming Pool Algae: What it is and How to Remove It. Chlorine is a useful tool for pool chemistry, but it has damaging effects. Hello , This is an inactive thread. Step 1:Ensure that the pump is running. Some sources online think that the suppressed pH means stronger chlorine (which would not apply in pools with CYA). Water clarity has to do with filtration, circulation, and chemistry. Boraxo is soap or laundry detergent. This article describes the types of algae and how you can prevent it. This controlled pH level means you wont need to worry about getting rid of nasty algae. The main benefit of borates is that they help buffer the pH from rising. If you use boric acid to increase borate in the water, it will only lower pH by 0.2 and have no effect on TA. The chemical formula of this compound isBO3. Others say it's because of borates' algaestat properties. Step 3: After 24 hours, check the borate, pH and TA levels to ensure that the chemicals are all within their proper levels. Remember that you should test your pool water as often as you can. Lumberton Borates disrupt cell wall development, metabolism and cell division. Borax has a pH of about 9.2 and it will raise the pH of the pool water when added. Nevertheless, both U.S. EPA assessments (2008b; 2015) indicate that an application rate resulting in a concentration of 35 mg/L (as boron) is currently authorized under FIFRA. WaterShapes January 27th, 2022 The Power of Plants, Centurion Swimmer, and Project Rescue, WaterShapes January 13th, 2022 Desert Invention, What is Graphene, and Fountains for Winter. 2.3.2 Dissociation of Boric Acid in Water. The output of this chemical is a salt that is a multi-functioning asset for swimming pool chemistry. Tetraborate products have a high pH and require acid to neutralize them when added into the pool, whereas boric acid needs no pH correction when it's added to water. 10 NSF.org (2019). An extra benefit borates not only makes the water healthy, but it also prevents swimmers from getting dry skin and red, itchy eyes. Metals may be dissolved in the water and may be at the saturation point for that pH, alkalinity and hardness. Our team of pool experts is ready to help. Chlorine becomes a lot less effective once this pH threshold is reached, allowing bacteria to form. Pools equipped with SWG or ECG (electronic chlorine generator) will benefit from a level of borate of 50 to 70 ppm, however, the US EPA and NSF do not recommend levels more than 50 ppm. You will need to buy some borate test strips. Over time with water loss from backwashing, filter cleaning, splash out, drag out and other water loss, (but not evaporation), you will need to bring the level back up to 50 ppm or more. Is it defined anywhere else?) At least a dozen articles and forum posts online talked about how borates are algaecides and algaestats. If you do your own research online (like we did), you will see dozens of opinions about borates. It is no problem and there are some benefits from higher levels but never more than 70 ppm. At 77F/25C: Now let's apply this to swimming pools.
First, if there are any metals in the water (copper, iron or manganese) there is a possibility of causing a stain.
The claim is up to 30-50% chlorine savings, but that's theoretical at best. The only way to do this is to know the borate level in the water. Borate does a great job regulating your water and keeping it well balanced. Provide fresh water outside and change it regularly. Chlorine stops working, making the water cloudy, promotes water bacteria and algae growth. Water needs a minimum sanitizer level to stay sanitized. Second, to offset the high pH of the Borax you will need to add muriatic acid (31.45% HCl). It is generally known that residential pools lose, on average, about 1 to 2 ppm of chlorine per day. And when we say buffering, we mean the chemistry resists change in pH.
This is a minimum of 33% less chlorine. 14. What follows are some of the most impactful reasons to treat your water with borate. However, most of the chemicals you can treat with have long names and even longer explanations on what it will do for your pool. Borate as a pH buffer: Buffering is when the water resists changes in pH when acid or base are added to it. WaterShapes March 31st, 2022 An Aquarium Saves a City, A Big Fountain, and Working with Turnover Calculations. But according to this thread, the reason it's expressed as B(OH)3 is because unlike most acids, whichdissociate in water, boric acid is associated with water. As mentioned above, the pKavalue is where the buffering system can resist change in pH the best. Yeah, there's a lot to unpack here. So, if you have had problems with metal stains in the past or if you are using well water, you should consider testing the water for metals and then using a metal remover, stain inhibitor chemical (called sequestering agents) or using another borate-containing product such as boric acid or a borate pH neutralized product instead of Borax (see below). It is usually expressed as grams/kilogram (g/kg). It helps to reduce the use of chlorine and prevents algae growth. 2 Researching this article involved over 30 websites, peer-reviewed journals, and other chemistry publications. Borate is only lowered by water loss splash out, drag out, leaks, filter backwashing, or draining. Because boric acid/borates buffer pH, they contribute in a small way to total alkalinity. Borates' LSI impact is pretty small compared to Cyanuric Acid (CYA), but it's enough that we have included it as an optional factor in the Orenda Calculator. WaterShapes March 17th, 2022 Restoring a Simple Classic, Subterranean Adventure and a Masterful Florida Garden. Boron Chemistry.
Because of their pH buffering capability, borates impact the Langelier Saturation Index (LSI), particularly when the pH is high. 8. This is because more chlorine means more costs, along with the typical side effects it offers. Borates are gaining popularity and are now widely recommended for pools, and for good reasons: For starters, adding borate is a one-time chemical affair.
We neither encourage nor discourage the use of Borates. We are a registered 501(c)3 non-profit that is funded by user donations. But why use it in the first place? Some say Boric Acid is expressed as B(OH)3, while others have it as H3BO3. Slowing the growth/reproduction rate, as we cover in-depth in. A good tip is to put a chair on the top step of the pool access. Beaumont
In our 20+ years of experience in the swimming pool industry, we highly recommend ProTeam Supreme Plus. "So how do borates prevent algae?
In our opinion, if you already are using Henrys Law to your advantage you can contain pH without borates because you can already determine your pH ceiling. Most of us don't pay a lot of attention to actual Borate levels but the recommended level is 30-50. Pool Calculator makes pool chemistry easy. Also Available for iOS & Android. The TA must be lower than 140 ppm and the Hardness must be less than 350 ppm before adding Borax. The Woodlands, Tomball - Robert W. Lowry, pg. In addition, before adding the Borax, the alkalinity should be about 80 ppm and the pH should be about 7.4 or less. But even so, the chlorine savings would be minimal. What are Free Chlorine, Combined Chlorine, and Total Chlorine? Also, if you have metals in the water or have had metal staining, boric acid will not cause additional staining, deposits, or precipitation. Most of the time the pH drop is only about 0.2 for a 50 ppm dose. Borate is a buffer against pH increase so this means less calcium carbonate scaling on the hydrogen gas (H2) generation plate (negative electrode) of the SWG.
The pump has run continuously. Borate usage also provides you with soft water. Some manufacturers claim 50% reduction in chlorine consumption. And since borates are in our calculator, we're here to explain what they are and how they work in this article. The ONLY chlorine savings is if you arent using a high enough active chlorine level.
That should be its only side effect and it is a benefit. if(typeof ez_ad_units!='undefined'){ez_ad_units.push([[250,250],'poolcalculator_com-medrectangle-4','ezslot_5',155,'0','0'])};if(typeof __ez_fad_position!='undefined'){__ez_fad_position('div-gpt-ad-poolcalculator_com-medrectangle-4-0')};This fact about borate is 100% true! Borate test strips are made by LaMotte, ITS, Hach and Taylor. You can use the effects of adding chemicals at the bottom of PoolMath to see how much adding borax will raise ph vs raising borate level. Sugar Land
The benefits of using borate are truly impressive: Except for the last two points, these are not just manufacturer or sales claims but proven benefits when the concentration of borate in the water is 50 ppm. Borates, like CYA, do not evaporate out of the pool, so they tend to stay at approximately the same level most of the year. In the 2008 Tolerance Reassessment Eligibility Decision (TRED), the U.S. EPA (2008b) selected a no observable adverse effect level (NOAEL) of 8.8 mg/kg-day (as boron) from a chronic toxicity study in dogs in order to assess the margin of exposures for various residential uses of boron (including its use in swimming pools). If you use sodium tetraborate pentahydrate (lets just use tetraborate) you will increase pH and TA in addition to raising borate in the water. If more light can get into the water, or if it reflects better, the water can appear cleaner and clearer.
7 Lowry, Robert W. (2018). Both of these buffering equilibriums have an optimal pH where they can resist change in pH.
Cost is not the only consideration in choosing a borate product. 6 Kabay, Bryjak, et.al. Little did he know that his product would revolutionize the way we clean our swimming pools. So borates are good perhaps at preventing algae (algaestatic) rather than killing algae (algicidal). WaterShapes February 24th, 2022 Vinyl Advancements, Combing Fish and Crops, and Vintage Garden Influence. Borate users have their own opinions on how they have impacted their pools. Read on to learn about Free chlorine, combined Chlorine, and Total chlorine. Adding 76 oz or 4.75 lbs of boric acid per 10,000 gallons of water will provide 10 ppm of borate.
1 Here are two resources with borate dosing information: PHTA and Pool Chemistry Training Institute. In other words, bureaucracy at its finest. So, you will need to add acid less frequently. Pool Calculator Swimming Pool Water Testing Basicsif(typeof ez_ad_units!='undefined'){ez_ad_units.push([[336,280],'poolcalculator_com-box-4','ezslot_3',149,'0','0'])};if(typeof __ez_fad_position!='undefined'){__ez_fad_position('div-gpt-ad-poolcalculator_com-box-4-0')}; One of the most visible benefits of using borate in the pool is the crystal-clear water. This claim ties into the previous two claims about pH buffering and algae prevention.
What do borates do in swimming pool chemistry? There are few things that can spoil your day more than cloudy water in your pool. Every reputable source we read and spoke with agreed themaximumborate level in a pool is 50 ppm. document.getElementById( "ak_js" ).setAttribute( "value", ( new Date() ).getTime() ); 140 Lomas Santa Fe Dr Ste 202 We have not heard customers of ours talking about major chlorine savings on their borate pools. (2008). Therefore, you can add boric acid without having to add muriatic acid like when adding Borax or sodium tetraborate pentahydrate. With the use of borate, you can keep your chlorine usage to a minimum, which greatly benefits the swimmers in your pool. This article is dedicated to the memory of Robert W. Lowry, long-time, instructor, author and chemist, and co-founder of the Pool Chemistry Training Institute. Boric acid, formula B(OH)3 or H3BO3, is technically a Lewis acid. Algae require CO2 to carry out photosynthesis so removing CO2 would kill algae. Slowing the growth/reproduction rate, as we cover in-depth in Pillar 3, can improve chlorine efficiency because sanitization is a race between the kill rate of the sanitizer and the reproduction rate of the contaminant. This requires adding a large amount of acid to lower TA back to a target of 90 ppm which will lower pH much lower than 7.0. Check the borate level about once a month. In swimming pools, borate products are primarily used as a pH buffering system in water; specifically to buffer against the increase in pH. Pages 13-24.
So baking soda and borates are required to be registered as a pesticide in California and all toxicity, cancer and exposure tests must be done prior to approval and then the companies selling these products have to pay a use fee to the State for every pound sold. Whenever the level gets near 30 ppm, you should add sufficient borate to bring it back to 50-60 ppm. Look where boric acid and borate intersect on the graph above. Carbonic acid is a "Bronstead acid" that dissociates in water and loses a Hydrogen ion. of pool water to get sick, assuming the pool is at 30-50 ppm borate. High pH levels will result in calcium scaling, based on pool surfaces, water lines, and accessories, especially in salt water pools. Take a look at the following information: You should consider adding borates to your pool if you dont want this to happen to your swimming pool. The savings would occur if your chlorine falls behind (which is most pools, let's be honest). I added 65 ounces about 24 hours ago. No problem with high pH and alkalinity either. Acute oral LD50 for boric acid in laboratory animals is in the range 2.5-5 g/kg; about the same as table salt (NaCl: LD50 3-4 g/kg). That's because of how borate products are classified by the California EPA: "The State of California has a unique law with regard to what they define as "water modifiers" under a pesticide category of "spray adjuvants." Upon further reading, of those 30+ open tabs on our browser, most of them were just paraphrasing (or outright plagiarizing) only a handful of original sources. The Orenda App (version 3.0 and later) will show you this in real-time. Am still wondering once I get my borate level to 50 if there is any problem going over 50 when I need to raise ph in the future or if I need to switch to soda ash, because continuing to use borate will raise the borate level.
Soft water is water without many harmful chemicals. This means your water will be clear as day, and you will not have to worry about murky water forming in your pool. BellaireKatyCypress Stabilizing pH helps with balance-related concerns, and by reducing chlorine demand, it helps mitigate todays skyrocketing costs. 50 ppm borate lowers the free chlorine recommendation from 7.5% to 5%." For an individual weighing 70 kg (150 lbs), this would indicate more than 150 g or 5.3 oz of pure boric acid for lethal effect. It does not decompose, get used up or expire. It is important to keep your pools total alkalinity (TA) and pH in the recommended levels, if either is out of balance, it will affect the function of all chemicals in your pool, including chlorine. This means the pH ceiling is reduced when you have borates in your pool. - Richard Falk 9. Chlorine in high and direct exposure has been linked to skin cancers and other harmful diseases (Source). But experts disagree on how much chlorine savings borates can actually provide. 4 This confused us because there are reputable sources that have Boric acid written in two different ways. Sea water contains about 4.5 ppm boron and some saline lakes contain above 300 ppm boron. To paraphrase Richard, if you already have enough chlorine to stay ahead of the reproduction rate of algae, you will not notice chlorine savings, because it's being used up properly.
14 Lowry, Robert W. (2018). We'll save you some time: none of those theories are true. The fact is that algae can get plenty of carbon or carbon dioxide (CO2) from the carbonates (CO 2) and bicarbonates (HCO ) in the water (TA). According to Robert Lowry, they also slow the growth of algae, which can improve chlorine efficiency. WaterShapes February 10th, 2022 Beach Entry on the Beach, Innovation in Ruin, and a Waterproofing Webinar. Save my name, email, and website in this browser for the next time I comment. Less chlorine since borates help prevent algae growth, you may use less chlorine which means you will save money in monthly chemical costs. Navigating the Chemical Requirements of the Model Aquatic Health Code. If you are using any product that is not specifically labeled for use in swimming pools and/or lacks those certifications, we advise against using those products in your pool.11. Call us at 1.281.870.1600 (Houston), 1.409.898.4995 (Beaumont), or 1.361.575.0183 (Victoria). Honestly, we don't know if borates provide improved water clarity directly or indirectly.
Posted on the TFP forum. All Rights Reserved. Many circumstances happen when the pH in your pools water is not in balance. From a study of fewer individuals, dogs may be about 4-fold more sensitive. The chloramine doesnt develop quickly versus those who dont include a borate agent as part of their pool maintenance.
And anecdotal evidence is often compelling, it's just not measurable. It's where the acid and its conjugate base intersect. It is being practiced by thousands of pool owners just like you. 59. Your email address will not be published. You will need less chlorine (have a lower chlorine demand) when using borates because you are preventing algae. In fact, you just add it and in about 12 hours or so, you test pH and alkalinity and adjust them if necessary.
Practical first-hand knowledge is probably more valuable than purely theoretical numbers. Boric Acid is a much easier way to add Borates, but too each their own. Borates stabilize pH, reduce algae growth, Navigating the Chemical Requirements of the Model Aquatic Health Code. Port Arthur, LOCATIONSHouston: 281-870-1600Beaumont: 409-898-4995 Copyright 2022 Platinum Pools All Rights Reserved, Platinum Pools Houston
From accidental poisonings in humans, minimum oral lethal doses of boric acid have been estimated to be in the range of 5-20 g for adults, 3-6 g for children. A good borate contains a chlorine stabilizer that prevents ultraviolet light from consuming the chemical. And the more borate you have in your water, the less exposure (or consumption of pool water) is needed for adverse health effects. 9.2. You may be wondering who came up with the idea of adding borates to a swimming pool. Corrodes metallic accessories (heater, steps). 12 US Environmental Protection Agency. (2015). Basically, the benefits of borates can be boiled down to these four things: The carbonate alkalinity system is the dominant buffering system used in swimming pools, and it buffers against changes in pH, especially against reducing pH. It is fairly easy to teach pets not to drink from the pool. However, finding boric acid in your area may be difficult. The amount needed is 3 gallons or 10 boxes of Borax or 2 fl oz of muriatic acid for each 1 oz of Borax added. His published information on borates is perhaps the most concise, yet detailed source out there. Designed Powered By GrossiWeb. Borates also stay in the water for a very long time. WaterShapes April 14th, 2022 A pool for Robust Exercise, the Power of Showers, a Pool Hydrant Detail, and more. Boron Separation Processes. They are: 3 Kochkodan, Hilal, et.al. A high pH can trigger health problems such as burning in the eyes and nose, and dryness, itching of the skin and scalp. You can buy the products at other stores, but not pool stores. The Pool Volume Calculator makes it easy to calculate the volume of rectangular, oval, and circular pools quickly. His product buffers the pH and alkalinity and adds a sparkle and shine to the water. This has two potential problems. Helps stabilize the pH level using borates with a neutral pH level will help stabilize the chemicals in your pools water. Borates disrupt cell wall development, metabolism and cell division. This helps to slow the rise in pH, making it easier to contain pH.
So, borate is good at reducing chlorine demand because you are preventing algae. Other benefits depend on whom you're asking. The Orenda Calculator does the math for you, just like it takes CYA into account. Back in the 1980s, John Galvin founded ProTeam Pool Supplies and introduced ProTeam Supreme (sodium tetraborate). Then, brush the sides of the pool. Pool Chemistry for Residential Pools. More on health and safety later in this article. So borates arenot an algaecide, but according to Lowry, they can help prevent algae reproduction (at least one Sodium Tetraborate product does have an EPA registration as an algaestat). The pH may still rise, but not as dramatically. Borate is the conjugate base of boric acid. When the pH is raisedby adding Borax the metals may precipitate out causing a stain.
According to Lowry's textbook Pool Chemistry for Residential Pools: "So how do borates prevent algae? On the graph below, you can see the optimal buffering pH is where the lines intersect. There is none to humans unless they drink a lot of high borate pool water. Copyright , Pure Planet Science & Technology, Inc. is very weak and does not dissociate in aqueous solution as a Bronsted acid but it acts as a Lewis acid by accepting a hydroxyl ion to form the tetrahydroxyborate ion", Boric acid + water Tetrahydroxyborate + Hydrogen, is the conjugate base of carbonic acid. The product has a neutral pH, and you dont need to mix it with acid to reduce the levels. I have been adding 20 Mule Team Borax over the last week among other things as I have been trying to get my water balanced. Borax (not Boraxo): The chemical name issodium tetraborate decahydrate, formula Na2B4O710H2O. The only potential risk of borates is to dogs drinking the pool water.
Part of that criteria is dosing information. Using borate as a buffer with an SWG slows the rate of pH rise. It may not display this or other websites correctly. Most visitors online was 3404 , on Jan 24 2020, So you want to add borates to your pool--Why and How, With over 300,000 members, TFP is the largest and most influential pool & spa website on the Internet. California EPA says that if a product is used to modify the pH of water to maximize the performance of a pesticide (proper pH and alkalinity improves the performance of chlorine) then it is subject to all the same regulations as a pesticide. This means that you will not need to worry as much about potential side effects of pool use, such as red eyes, dry and itchy skin, and much more. For more information on how to care for your swimming pool, see our blogs on Pool Maintenanceif(typeof ez_ad_units!='undefined'){ez_ad_units.push([[336,280],'poolcalculator_com-banner-1','ezslot_2',142,'0','0'])};if(typeof __ez_fad_position!='undefined'){__ez_fad_position('div-gpt-ad-poolcalculator_com-banner-1-0')}; Testing your pool helps keep your water safe from viruses, bacteria, and algae, and ensures chemical levels are safe and comfortable. This point is called the pK, value depends on water temperature, but it doesnt change all that much. Most of the TA in pool water is made up of bicarbonate.
50 is the level I am going for correct? It is often found in grocery stores in the laundry aisle. Once you have your borate level established, you only lose it from backwash, splashout, or other water loss. I will take another reading in the morning. In our opinion, borates may be beneficial, but if you contain pH with lower carbonate alkalinity (which reduces your pH ceiling to a manageable level), we do not think they are necessary. The pKa value depends on water temperature, but it doesnt change all that much. How does borate prevent algae? Copyright 2022 Pool and Spa Resources, LLC. And since no other pool chemicals that we know of contain borate (unlike stabilized chlorines containing CYA), accumulation should not be an issue. Ch. Many articles claim that borate is an algaecide and that borate works as an algaecide by removing CO2 from the water. Logical but wrong. 5 University of Arizona Biology Department (2004). The closer your pH gets to the pKa value, the more resistance it faces.
Keeping TA at 90 ppm, cyanuric acid at 30-50 ppm and borate at 50 ppm, makes an ideal overall buffering system against up or down pH changes. Many of the questions we hear about borates are about their toxicity and health impacts on water. Clarity and "sparkle" are about how light penetrates and reflects in the water. Borates are an entirely different buffering mechanism.
For a better experience, please enable JavaScript in your browser before proceeding. Remember that our team at Platinum Pools is ready to help you with any questions and all other poo-related inquiries. Have been reading through pool school and came across the borate sticky and why they are a good idea. Those main sources are the basis for this article.
Because borates impact the LSI, we have included borates in our Orenda App 3.0 update. Higher pH levels are associated with higher levels of algae in the water, and borate prevents this from happening. Other Waterfeatures (from birdbaths to lakes), Outdoor Living, Fire Features, Amenities & Lighting, Landscape & Hardscape Materials/Equipment, Keeps the pH of the water from going up (pH buffer against rises in pH), Helps prevent algae (it is an algaestat, not an algaecide), Lowers chlorine demand (preventing algae lowers the need for chlorine), Helps protect HOCl (hypochlorous acid the killing form of free chlorine) from UV destruction. Because borates contribute to total alkalinity, just like CYA, the carbonate alkalinity is lower (relative to total alkalinity). This requires addition of sodium bicarb to raise alkalinity. Apply Supreme Plus directly to the pool or through the skimmer. 68. On the graph below, you can see the optimal buffering pH is where the lines intersect. (2015). None of the sources online cited any studies about this. 9 Copied/pasted from an email conversation with Richard Falk during his review of this article pre-publication. Using the MAHC. The reason is simple: TFPC (Trouble Free Pool Care) is a methodology, not a product that you must purchase. Service Industry News. There are plenty of options for pool owners when it comes to treating their water.
So to simplify, we will use the numbers at a water temperature of 77F (25C). When your pH level drifts past the level that is considered normal (around 7.8), something has to be done to fix it. 59. an algaecide, but according to Lowry, they can help prevent algae reproduction (at least one Sodium Tetraborate product does have an EPA registration as an algaestat). Here is the sticky I read about the benefits of borates. It buffers against reducing pH by taking or giving away a Hydrogen ion (H+). JavaScript is disabled. Are Borates Safe to Use? Ch. While we at Orenda do not endorse the use of borates, they are becoming more widely used.
Borate serves as a buffer for the pool. Both of these buffering equilibriums have an optimal pH where they can resist change in pH. You will need less chlorine (have a lower chlorine demand) when using borates because you are preventing algae. But again, we encourage you to form your own opinion and make an informed decision. We also spoke with Richard Falk about chlorine savings, and his answer was also clear: "There are NO chlorine savings at all from using borates or boric acid IF you maintain a high enough active chlorine level (FC/CYA ratio) such that chlorine is able to kill algae faster than it can reproduce. 59. Multiple reputable sources online give slightly different pK.
When we think of pH buffering, most of us have been taught to think in terms of Total Alkalinity (TA.) Borates should be approximately 50 ppm, TA 80-120 ppm and pH between 7.4 and 7.6. 20 Mule Team Borax is used to raise PHMuriatic acid will lower PH and Total Alkalinity at the same time. The purpose of this article was to explain what borates are and what they do in pool water. Boron Separation Processes. To calculate carbonate alkalinity, we must deduct cyanurate alkalinity and borates. Borate does not remove any CO2 from the water and even if it did, the next time soda ash or sodium bicarb is added, CO2 is added.
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